Structural Determination of a Short-Lived Excited Iron(II) Complex by Picosecond X-Ray Absorption Spectroscopy
Structural changes of the Fe(II)-tris-bipyridine ([FeII(bpy)3]2+) complex induced by ultrashort pulse excitation and population of its short-lived (?0.6 ns) quintet high spin state were detected by picosecond x-ray absorption spectroscopy. The structural relaxation from the high spin to the low spin state was followed over the entire lifetime of the excited state. A combined anal. of the x-ray-absorption near-edge structure and extended x-ray-absorption fine structure spectroscopy features delivers an Fe-N bond elongation of 0.2 A in the quintet state compared to the singlet ground state. [on SciFinder (R)]
Optical, Electron, and Mass Spectroscopy and Other Related Properties
Laboratoire de Spectroscopie Ultrarapide, ISIC,Ecole Polytechnique Federale de Lausanne,Lausanne,Switz.
written in English.
15025-74-8 (Tris(2,2'-bipyridine)iron(2+) Role: PRP (Properties) (ps x-ray spectra of short-lived excited)
Record created on 2007-05-31, modified on 2016-08-08