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research article

Broadband femtosecond fluorescence spectroscopy of [Ru(bpy)3]2+

Cannizzo, Andrea  
•
van Mourik, Frank  
•
Gawelda, Wojciech  
Show more
2006
Angewandte Chemie International Edition

Femtosecond fluorescence-upconversion studies of aq. [Ru(bpy)3]2+ show a short-lived vibrationally hot emission of the singlet metal-to-ligand charge-transfer state, with an ultrafast intersystem crossing (~ 10 fs) to the triplet state at const. energy (the colors indicate the luminescence intensity). [on SciFinder (R)]

Type
research article
DOI
10.1002/anie.200600125
Web of Science ID

WOS:000237533400035

Author(s)
Cannizzo, Andrea  
•
van Mourik, Frank  
•
Gawelda, Wojciech  
•
Zgrablic, Goran  
•
Bressler, Christian  
•
Chergui, Majed  
Date Issued

2006

Publisher

Wiley-VCH Verlag GmbH

Published in
Angewandte Chemie International Edition
Volume

45

Issue

19

Start page

3174

End page

3176

Subjects

Fluorescence up-conversion (broadband femtosecond fluorescence spectroscopy of [Ru(bpy)3]2+); Luminescence (hot; of [Ru(bpy)3]2+); Vibrational energy transfer (intramol.; of [Ru(bpy)3]2+); Intersystem crossing (of [Ru(bpy)3]2+); Intramolecular energy transfer (vibrational; of [Ru(bpy)3]2+)

•

ruthenium complex bipyridine fluorescence hot upconversion

Note

CAN 145:133174

73-5

Optical, Electron, and Mass Spectroscopy and Other Related Properties

Laboratoire de Spectroscopie Ultrarapide, ISIC, FSB-BSP Ecole Polytechnique Federale de Lausanne,EPFL SB ISIC LSU,Lausanne-Dorigny,Switz.

Journal

written in English.

15158-62-0 (Tris(bipyridine)ruthenium(2+) Role: PEP (Physical, engineering or chemical process), PRP (Properties), PYP (Physical process), PROC (Process) (broadband femtosecond fluorescence spectroscopy of [Ru(bpy)3]2+)

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSU  
Available on Infoscience
May 31, 2007
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/7472