Broadband femtosecond fluorescence spectroscopy of [Ru(bpy)3]2+

Femtosecond fluorescence-upconversion studies of aq. [Ru(bpy)3]2+ show a short-lived vibrationally hot emission of the singlet metal-to-ligand charge-transfer state, with an ultrafast intersystem crossing (~ 10 fs) to the triplet state at const. energy (the colors indicate the luminescence intensity). [on SciFinder (R)]


Published in:
Angewandte Chemie, International Edition, 45, 19, 3174-3176
Year:
2006
Keywords:
Note:
CAN 145:133174
73-5
Optical, Electron, and Mass Spectroscopy and Other Related Properties
Laboratoire de Spectroscopie Ultrarapide, ISIC, FSB-BSP Ecole Polytechnique Federale de Lausanne,EPFL SB ISIC LSU,Lausanne-Dorigny,Switz.
Journal
1433-7851
written in English.
15158-62-0 (Tris(bipyridine)ruthenium(2+) Role: PEP (Physical, engineering or chemical process), PRP (Properties), PYP (Physical process), PROC (Process) (broadband femtosecond fluorescence spectroscopy of [Ru(bpy)3]2+)
Other identifiers:
Laboratories:




 Record created 2007-05-31, last modified 2018-03-17


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