Comparison between nucleation of pentacene monolayer islands on polymeric and inorganic substrates
We present a comparative study of the nucleation and growth of pentacene monolayer islands in the submonolayer regime onto inorganic substrates of SiO2 and sapphire (Al2O3) and organic substrates of poly(methyl-metacrylate) (PMMA). We have determined the scaling laws that govern the saturated nucleation density per unit area N as a function of two essential deposition parameters: the deposition rate κ and the substrate temperature Ts. For all substrates, we found N∝κδ, with 0.8⩽δ⩽1.2, and the Ts dependence of the nucleation density follows a typical activated Arrhenius law. Whereas a critical nucleus size of i=2 is obtained for all investigated substrates, the activation energy for nucleation depends significantly on the dielectric. The difference in activation energy of nucleation on PMMA and SiO2 is due to different molecule-substrate interactions
WOS:000231564600070
2005
72
8
85211
Inst. Charles Sadron, Strasbourg, France
8602909
REVIEWED
EPFL