Facile, thermo-reversible cycloaddition of small molecules to a ruthenium(II) arene-diketiminate
2007
Abstract
Formation of a vacant coordination site on a Ru center permits an unusual binding of small molecules such as ethylene, acetylene, and dihydrogen, resulting in the transformation of the chelating β-diketiminate ligand to a β-diimine. These representative species are observed during the catalytic hydrogenation of styrene.
Details
Title
Facile, thermo-reversible cycloaddition of small molecules to a ruthenium(II) arene-diketiminate
Author(s)
Phillips, AD ; Laurenczy, G ; Scopelliti, R ; Dyson, PJ
Published in
Organometallics
Volume
26
Issue
5
Pages
1120-1122
Date
2007
Other identifier(s)
View record in Web of Science
DAR: 10177
DAR: 10177
Laboratories
LCOM
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCOM - Laboratory of Organometallic and Medicinal Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2007-03-30