Exploring the potential of europium(III) luminescence for the detection of phase transitions in ionic liquid crystals

The ionic liquid crystal [C12-mim]Cl has been doped with 5 mol% europium nitrate and the photophysical properties of both the ionic liquid and the trivalent europium ion have been monitored with respect to temperature in the range of 248 to +120 uC. The relative transition probabilities to the various ligand-field sub-levels are sensitive to the phase transitions, but the other photophysical parameters, lifetimes and overall intensities of the transitions to Eu(7F2) and Eu(7F4), display monotonous variation with temperature.

Published in:
Journal of Materials Chemistry, 17, 7, 654-657

 Record created 2007-02-15, last modified 2020-10-28

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