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  4. Enhancement of the piezoelectric response of tetragonal perovskite single crystals by uniaxial stress applied along the polar axis: A free-energy approach
 
research article

Enhancement of the piezoelectric response of tetragonal perovskite single crystals by uniaxial stress applied along the polar axis: A free-energy approach

Budimir, M.  
•
Damjanovic, D.  
•
Setter, N.  
2005
Physical Review B

The influence of the uniaxial bias stress on the piezoelectric properties of tetragonal BaTiO3 and PbTiO3 monodomain crystals is modeled in the framework of the phenomenological Landau-Ginzburg-Devonshire theory. It is shown that tensile and compressive stresses, both applied along the spontaneous polarization direction, reduce and enhance the piezoelectric response, respectively. The enhancement effect is due to the flattening of the free-energy profile and the corresponding dielectric softening of crystals, caused by the compressive stress. In BaTiO3 crystals, at temperatures close to the tetragonal-orthorhombic phase transition temperature, the free-energy profile flattening and dielectric softening are the largest along axes perpendicular to the polarization direction, facilitating thus the polarization rotation away from the 001 polar axis. The resulting enhancement of the shear piezoelectric coefficient is directly responsible for the increase of the longitudinal piezoelectric coefficient along the 111 axis. At temperatures deep within the tetragonal phase in BaTiO3, and over the whole ferroelectric region of PbTiO3, the flattening of the free-energy profile and the dielectric softening by compressive stress are the strongest along the polar axis. The resulting enhancement of the longitudinal piezoelectric coefficient is thus the largest along the polar 001 direction. These results, which can be applied to other perovskite crystals, have broad implications.

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Type
research article
DOI
10.1103/PhysRevB.72.064107
Web of Science ID

WOS:000231564400037

Author(s)
Budimir, M.  
Damjanovic, D.  
Setter, N.  
Date Issued

2005

Published in
Physical Review B
Volume

72

Issue

6

Article Number

064107

Subjects

lead-zirconate-titanate

•

morphotropic phase-boundary

•

high curie-temperature

•

orientation dependence

•

barium-titanate

•

0.7pb(mg1/3nb2/3)o-3-0.3pbtio(3) crystals

•

electromechanical properties

•

thermodynamic theory

•

thin-films

•

batio3

Note

Damjanovic, D EPFL, Mat Inst, Ceram Lab, CH-1015 Lausanne, Switzerland EPFL, Mat Inst, Ceram Lab, CH-1015 Lausanne, Switzerland

960BE

Cited References Count:43

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
August 21, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/233554
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