Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Conferences, Workshops, Symposiums, and Seminars
  4. Investigation of Local Electrochemical Performance and Local Degradation in an Operating Solid Oxide Fuel Cell
 
conference paper

Investigation of Local Electrochemical Performance and Local Degradation in an Operating Solid Oxide Fuel Cell

Wuillemin, Zacharie  
•
Müller, Andres  
•
Nakajo, Arata  
Show more
Dr. Steinberger-Wilckens, Robert
2008
Proceedings of the 8th EUROPEAN FUEL CELL FORUM 2008
8th EUROPEAN FUEL CELL FORUM 2008

In order to characterize a new SOFC stack design, to investigate degradation processes and to validate models, a diagnostic test station was designed and realized. It allows to characterize repeat-elements locally by measuring the local potential, current density and temperature over the active area. The active area is segmented in 18 small electrically insulated measurement points (segments), in addition to a main segment. The profile of current density was investigated up to an average of 0.6A/cm2 and 67% of fuel utilization, showing as expected a different response depending on the position along the flowpath. In addition, the local Nernst potentials were measured by temporarily disabling the polarization of the concerned segments. The temperature profile was also investigated as a function of the output current, showing a large heat transfer with the test furnace in this single-element configuration. In addition, local degradation behavior was studied over 1900 hours. In particular, it was found that the repeat-element showed a large sensitivity to fuel composition, with larger degradation rates under pure hydrogen than under diluted fuel mixture. Impedance spectroscopy results showed large differences in degradation behavior, depending on the location in the repeat-element and on the polarization history. In particular, segments that had not been polarized during the test showed lower ohmic resistances than the polarized ones, and zones located near the gas inlets degraded more than those near the outlet. With this experiment, it was clearly demonstrated that degradation processes depend on local operating conditions.

  • Files
  • Details
  • Metrics
Loading...
Thumbnail Image
Name

B1009.pdf

Access type

openaccess

Size

2.24 MB

Format

Adobe PDF

Checksum (MD5)

74aae22cff67a8e73d947ca3a9c2ca11

Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés