Electron-Affinity-Triggered Variations on the Optical and Electrical Properties of Dye Molecules Enabling Highly Efficient Dye-Sensitized Solar Cells
The synthesis, characterization, and photovoltaic performance of a series of indacenodithiophene (IDT)-based D--A organic dyes with varying electron-accepting units is presented. By control of the electron affinity, perfectly matching energy levels were achieved with a copper(I/II)-based redox electrolyte, reaching a high open-circuit voltage (>1.1V) while harvesting a large fraction of solar photons at the same time. Besides achieving high power conversion efficiencies (PCEs) for dye-sensitized solar cells (DSCs), that is, 11.2% under standard AM1.5G sunlight, and 28.4% under a 1000 lux fluorescent light tube, this work provides a possible method for the design and fabrication of low-cost highly efficient DSCs.
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Liu, Y., Cao, Y., Zhang, W., Stojanovic, M., Dar, M. I., Pechy, P., Saygili, Y., Hagfeldt, A., Zakeeruddin, S. M., & Graetzel, M. (2018). Electron-Affinity-Triggered Variations on the Optical and Electrical Properties of Dye Molecules Enabling Highly Efficient Dye-Sensitized Solar Cells. Angewandte Chemie International Edition, 57(43), 14125–14128. https://doi.org/10.1002/anie.201808609
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WOS:000447371500023
2018-10-22
57
43
14125
14128
REVIEWED
EPFL