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  4. Magnetic order in the quasi-one-dimensional Ising system RbCoCl3
 
research article

Magnetic order in the quasi-one-dimensional Ising system RbCoCl3

Hanni, N. P.
•
Sheptyakov, D.
•
Mena, M.
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March 17, 2021
Physical Review B

In RbCoCl3, the magnetic Co2+ ions form weakly coupled Ising chains arranged on a triangular lattice. We have investigated the structure and magnetism in RbCoCl3 by high-resolution x-ray diffraction and neutron scattering measurements on powder and single-crystal samples between 1.5 and 300 K. Upon cooling, the Co2+ spins develop one-dimensional antiferromagnetic correlations along the chain axis (c axis) below 90 K. Below the first Neel temperature, T-N1 = 28K, a partial three-dimensional magnetic order sets in, with propagation vector k(1) = (1/3, 1/3, 1), the moments aligned along the c axis, and every third chain uncorrelated from its neighbors. Only below a second magnetic phase transition at T-N2 = 13K does the system achieve a fully ordered state, with two additional propagation vectors: k(2) = (0, 0, 1) establishes a "honeycomb" c-axis order, in which one third of the chains are subject to a strong effective mean field due to their neighbors whereas two thirds experience no net field, while k(3) = (1/2, 0, 1) governs a small, staggered, in-plane ordered moment. We conclude that RbCoCl3 is an excellent material to study the physics of Ising chains in a wide variety of temperature-controlled environments, and our results build an important foundation for the accurate interpretation of the spin dynamics measured in each case.

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Type
research article
DOI
10.1103/PhysRevB.103.094424
Web of Science ID

WOS:000646413200005

Author(s)
Hanni, N. P.
Sheptyakov, D.
Mena, M.
Hirtenlechner, E.
Keller, L.
Stuhr, U.
Regnault, L-P
Medarde, M.
Cervellino, A.
Ruegg, Ch  
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Date Issued

2021-03-17

Published in
Physical Review B
Volume

103

Issue

9

Article Number

094424

Subjects

Materials Science, Multidisciplinary

•

Physics, Applied

•

Physics, Condensed Matter

•

Materials Science

•

Physics

•

neutron powder-diffraction

•

heisenberg-antiferromagnet

•

coordination polymers

•

crystal-structures

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anti-ferromagnets

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raman-scattering

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phase-transition

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cscobr3

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cscocl3

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LUQ  
LQM  
Available on Infoscience
June 5, 2021
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/178665
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