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  4. Phosphoric Acid-Catalyzed Enantioselective Transfer Hydrogenation of N-Aryl-ortho-Hydroxybenzophenone Ketimines
 
research article

Phosphoric Acid-Catalyzed Enantioselective Transfer Hydrogenation of N-Aryl-ortho-Hydroxybenzophenone Ketimines

Nguyen, Thanh Binh
•
Bousserouel, Hadjira
•
Wang, Qian  
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2011
Advanced Synthesis & Catalysis (ASC)

The first enantioselective chiral phosphoric acid-catalyzed transfer hydrogenation of N-aryl-ortho-hydroxybenzophenone ketimines using a Hantzsch ester as hydrogen source was developed to afford, after removal of the N-aryl group, the corresponding chiral diarylmethylamines in high yields and enantioselectivities.

  • Details
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Type
research article
DOI
10.1002/adsc.201000754
Web of Science ID

WOS:000287669600008

Author(s)
Nguyen, Thanh Binh
Bousserouel, Hadjira
Wang, Qian  
Guéritte, Françoise
Date Issued

2011

Publisher

Wiley-Blackwell

Published in
Advanced Synthesis & Catalysis (ASC)
Volume

353

Issue

2-3

Start page

257

End page

262

Subjects

diarylmethylamines

•

Hantzsch esters

•

ortho-hydroxybenzophenone ketimine

•

organocatalysis

•

phosphoric acids

•

transfer hydrogenation

•

Chiral Bronsted Acid

•

Alpha-Imino Esters

•

Organocatalytic Transfer Hydrogenation

•

Asymmetric Transfer Hydrogenation

•

Friedel-Crafts Reaction

•

Organometallic Reagents

•

Kinetic Resolution

•

Arylboronic Acids

•

3-Component Reaction

•

Reductive Amination

Editorial or Peer reviewed

NON-REVIEWED

Written at

EPFL

EPFL units
LSPN  
Available on Infoscience
August 31, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/70604
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