Controlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium
Decomposition into higher species: Intramolecular UIII-mediated homolytic C-O bond cleavage in UIII (alkoxy)siloxy complexes at low temperature and subsequent reduction with KC8 led to unprecedented polymetallic complexes containing siloxy, silanediolate, and silanetriolate ligands (see example: U green, Si yellow, K blue, O red). Such compounds may be useful precursors to uranium ceramics relevant for catalysis and the storage of spent nuclear fuel. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Camp, C., Kefalidis, C. E., Pecaut, J., Maron, L., & Mazzanti, M. (2013). Controlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium. Angewandte Chemie International Edition, 52(48), 12646–12650. https://doi.org/10.1002/anie.201307291
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WOS:000327582900032
2013
52
48
12646
12650
REVIEWED
OTHER