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research article

Magnetic exchange parameters and anisotropy of the quasi-two-dimensional antiferromagnet NiPS3

Lancon, D.  
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Ewings, R. A.
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Guidi, T.
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October 9, 2018
Physical Review B

Neutron inelastic scattering has been used to measure the magnetic excitations in powdered NiPS3, a quasitwo-dimensional antiferromagnet with spin S = 1 on a honeycomb lattice. The spectra show clear, dispersive magnons with a similar to 7 meV gap at the Brillouin zone center. The data were fitted using a Heisenberg Hamiltonian with a single-ion anisotropy assuming no magnetic exchange between the honeycomb planes. Magnetic exchange interactions up to the third intraplanar nearest neighbor were required. The fits show robustly that NiPS 3 has an easy-axis anisotropy with Delta = 0.3 meV and that the third nearest neighbor has a strong antiferromagnetic exchange of J(3) = -6.90 meV. The data can be fitted reasonably well with either J(1) < 0 or J(1) > 0, however, the best quantitative agreement with high-resolution data indicates that the nearest-neighbor interaction is ferromagnetic with J(1) = 1.9 meV and that the second nearest-neighbor exchange is small and antiferromagnetic with J(2) = -0.1 meV. The dispersion has a minimum in the Brillouin zone corner that is slightly larger than that at the Brillouin zone center, indicating that the magnetic structure of NiPS3 is close to being unstable.

  • Details
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Type
research article
DOI
10.1103/PhysRevB.98.134414
Web of Science ID

WOS:000446900200003

Author(s)
Lancon, D.  
Ewings, R. A.
Guidi, T.
Formisano, F.
Wildes, A. R.
Date Issued

2018-10-09

Publisher

AMER PHYSICAL SOC

Published in
Physical Review B
Volume

98

Issue

13

Article Number

134414

Subjects

Materials Science, Multidisciplinary

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Physics, Applied

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Physics, Condensed Matter

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Materials Science

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Physics

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visualization

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order

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model

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mps3

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mn

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fe

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ni

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LQM  
Available on Infoscience
December 13, 2018
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/152593
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