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research article

Superhalogen Passivation for Efficient and Stable Perovskite Solar Cells

Kim, Hobeom  
•
Lim, Jaekeun
•
Sohail, Muhammad
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April 30, 2022
Solar Rrl

Metal-halide perovskites are optoelectronic materials applied to solar cells as a light absorber due to their excellent optoelectronic properties. The power conversion efficiency of perovskite solar cells (PSCs) reaches 25.7% certified, which stands in comparison with Si solar cells. Importantly, compositional engineering of perovskites has been one of the keys to the breakthrough. However, the presence of defects within perovskites is a matter of importance as it can cause nonradiative recombination of charge carriers. In addition, defect migration can degrade the photovoltaic performance and stability of PSCs. Previous studies have commonly addressed that iodide-related defects such as interstitial iodide and iodide vacancy are problematic due to their low formation energy. Thus, halide engineering is imperative to mitigate the defect-related dynamics and improve the materials quality of perovskites. In this sense, superhalogen is a promising candidate for defect passivation and stabilization of perovskites based on its higher electronegativity and electron affinity than halides, which are beneficial to the formation of a more robust interaction with adjacent elements in perovskites. This perspective gives an overview of studies regarding the use of superhalogen to develop efficient and stable PSCs and concludes with an outlook of further research directions.

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Type
research article
DOI
10.1002/solr.202200013
Web of Science ID

WOS:000789551800001

Author(s)
Kim, Hobeom  
Lim, Jaekeun
Sohail, Muhammad
Nazeeruddin, Mohammad Khaja  
Date Issued

2022-04-30

Publisher

WILEY-V C H VERLAG GMBH

Published in
Solar Rrl
Volume

6

Issue

7

Article Number

2200013

Subjects

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Materials Science

•

defect passivation

•

ion migration

•

perovskite solar cells

•

perovskites

•

superhalogen

•

photovoltaic performance

•

stability

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GMF  
Available on Infoscience
May 23, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/187989
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