Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. High-pressure infrared spectroscopy: Tuning of the low-energy excitations in correlated electron systems
 
research article

High-pressure infrared spectroscopy: Tuning of the low-energy excitations in correlated electron systems

Kezsmarki, I.
•
Gaal, R.  
•
Homes, C. C.
Show more
2007
Physical Review B

We have extended the range of the high-pressure optical spectroscopy to the far-infrared region keeping the accuracy of ambient-pressure experiments. The developed method offers a powerful tool for the study of pressure-induced phase transitions and electronic-structural changes in correlated electron systems as the optical pressure cell, equipped with large free-aperture diamond window, allows the measurement of optical reflectivity down to omega approximate to 20-30 cm(-1) for hydrostatic pressures up to p approximate to 26 kbar. The efficiency of the technique is demonstrated by the investigation of the two-dimensional charge-density-wave 1T-TaS2 whose electronic structure shows high sensitivity to external pressure. The room-temperature semimetallic phase of 1T-TaS2 is effectively extended by application of pressure and stabilized as the ground state above p=14 kbar. The corresponding fully incoherent low-energy optical conductivity is almost temperature independent below T=300 K. For intermediate pressures, the onset of the low-temperature insulating phase is reflected by the sudden drop of the reflectivity and by the emergence of sharp phonon resonances.

  • Files
  • Details
  • Metrics
Loading...
Thumbnail Image
Name

article_3.pdf

Access type

openaccess

Size

813.77 KB

Format

Adobe PDF

Checksum (MD5)

d551c0b601d583db937b182f842117b1

Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés