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research article

Nanowire Perovskite Solar Cell

Im, Jeong-Hyeok  
•
Luo, Jingshan  
•
Franckevicius, Marius  
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2015
Nano Letters

Organolead iodide perovskite, CH3NH3PbI3, was prepared in the form of nanowire by means of a small quantity of aprotic solvent in two-step spin-coating procedure. One-dimensional nanowire perovskite with the mean diameter of 100 nm showed faster carrier separation in the presence of hole transporting layer and higher lateral conductivity than the three-dimensional nanocuboid crystal. Reduction in dimensionality resulted in the hypsochromic shift of both absorption and fluorescence spectra, indicative of more localized exciton states in nanowires. The best performing device employing nanowire CH3NH3PbI3 delivered photocurrent density of 19.12 mA/cm(2), voltage of 1.052 V, and fill factor of 0.721, leading to a power conversion efficiency (PCE) of 14.71% at standard AM 1.5G solar illumination. A small I-V hysteresis was observed, where a PCE at forward scan was measured to be 85% of the PCE at reverse scan.

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Type
research article
DOI
10.1021/acs.nanolett.5b00046
Web of Science ID

WOS:000351188000103

Author(s)
Im, Jeong-Hyeok  
Luo, Jingshan  
Franckevicius, Marius  
Pellet, Norman  
Gao, Peng  
Moehl, Thomas  
Zakeeruddin, Shaik Mohammed  
Nazeeruddin, Mohammad Khaja  
Graetzel, Michael  
Park, Nam-Gyu
Date Issued

2015

Publisher

American Chemical Society

Published in
Nano Letters
Volume

15

Issue

3

Start page

2120

End page

2126

Subjects

nanowire

•

perovskite

•

CH3NH3PbI3

•

solar cell

•

aprotic solvent

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GMF  
LPI  
Available on Infoscience
May 29, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/114567
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