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research article

X-ray study of phase transitions in CS3Sb2I9 crystal

Bagautdinov, B. S.
•
Novikova, M. S.
•
Aleksandrova, I. P.
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1999
Solid State Communications.

An X-ray study of three phase transitions (PTs) at 86, 78 and 72 K has been carried out for the trigonal modification of the Cs3Sb2I9 crystal (space group P-3m1, a = 8.460 Angstrom, c = 10.398 Angstrom). The T-c1 = 86 K PT preserves the trigonal symmetry and is associated with the doubling of the c-parameter. At T-c2 = 72 K a doubling of a and b is observed. An intermediate incommensurate phase with q(1) = 1/2c*, q(2) = (1/2 - delta)a* + 1/2c* has been detected in the temperature range of 78-72 K. The lock-in PT at 72 K has a first order character. (C) 1999 Published by Elsevier Science Ltd. All rights reserved. [References: 4]

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Type
research article
DOI
10.1016/S0038-1098(99)00217-3
Author(s)
Bagautdinov, B. S.
Novikova, M. S.
Aleksandrova, I. P.
Blomberg, M. K.
Chapuis, G.  
Date Issued

1999

Published in
Solid State Communications.
Volume

111

Issue

7

Start page

361

End page

366

Subjects

Ferroelectrics

•

X-ray scattering

•

Phase transitions.

•

Cs3bi2i9.

•

Applied Physics/Condensed Matter/Materials Science in Current Contents(R)/Physical

•

Chemical & Earth Sciences.

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCR  
Available on Infoscience
March 7, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/227313
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