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  4. Kinetics of Ion-Exchange Reactions in Hybrid Organic-Inorganic Perovskite Thin Films Studied by In Situ Real-Time X-ray Scattering
 
research article

Kinetics of Ion-Exchange Reactions in Hybrid Organic-Inorganic Perovskite Thin Films Studied by In Situ Real-Time X-ray Scattering

Greco, Alessandro
•
Hinderhofer, Alexander
•
Dar, M. Ibrahim  
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December 6, 2018
The Journal of Physical Chemistry Letters

The exchange of ions in hybrid organic inorganic perovskites with the general formula APbX(3) (A = MA, FA; X = I, Cl, Br) is studied in five different systems using in situ real-time grazing incident X-ray diffraction (GIXD). In systems where the organic cation is exchanged, we find a continuous shift of the lattice parameter. The relative shift compared to the pure materials is used to quantify the exchange. Whether or not a conversion is possible, as well as the amount of exchanged cations, depends on the halide used. In the case of the interconversion of MAPbI(3) and MAPbCl(3), we observe a decay of the diffraction peaks of the original perovskite and the emergence of new peaks corresponding to the structure with the alternative halide. Moreover, we determined the relevant time scales of the growth and decay of the perovskite structures.

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Type
research article
DOI
10.1021/acs.jpclett.8b02916
Web of Science ID

WOS:000452929200013

Author(s)
Greco, Alessandro
Hinderhofer, Alexander
Dar, M. Ibrahim  
Arora, Neha  
Hagenlocher, Jan
Chumakov, Andrey
Gratzel, Michael  
Schreiber, Frank
Date Issued

2018-12-06

Publisher

AMER CHEMICAL SOC

Published in
The Journal of Physical Chemistry Letters
Volume

9

Issue

23

Start page

6750

End page

6754

Subjects

Chemistry, Physical

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Physics, Atomic, Molecular & Chemical

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

Physics

•

organolead halide perovskite

•

chloride

•

trihalide

•

emergence

•

cells

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
December 26, 2018
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/153194
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