An electron cyclotron system (ECS) is required in the European DEMO fusion reactor for plasma heating, magnetohydrodynamic control, especially the suppression of neoclassical tearing modes (NTMs), and thermal instability control. Microwave beams of 2 MW, generated by gyrotrons, shall propagate through corrugated HE 11 waveguides (WGs) of 63.5-mm inner diameter and finally reach specific locations in the plasma by a dedicated set of mirrors. The deployment of the beam may be done either by angular steering, i.e., tilting moveable mirrors, or by frequency steering, i.e., tuning the gyrotron frequency. In the last option, for long pulse operations, broadband optical grade diamond windows are required as confinement and/or vacuum barriers both at the torus and the gyrotron side. The Brewster-angle window represents a promising solution due to its intrinsic simplicity. However, the WG aperture imposes a minimum Ø180 mm for the disk at the Brewster-angle of 67.2° for diamond. This is an ambitious target, considering 140 mm as the state of the art. First, this article shows the very promising results of diamond growth experiments carried out by Diamond Materials GmbH with the first worldwide free-standing optical grade Ø180-mm disk having an average unpolished thickness of 1.3 mm. For the first time, one side of this large disk was polished and loss tangent measurements were performed at the center and over a large area. Then, the performance of the window featuring these large disks was characterized by a consistent set of thermomechanical analyses in view of the forthcoming window prototyping activity.