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  4. Mid-infrared photothermal heterodyne spectroscopy in a liquid crystal using a quantum cascade laser
 
research article

Mid-infrared photothermal heterodyne spectroscopy in a liquid crystal using a quantum cascade laser

Mertiri, Alket
•
Jeys, Thomas
•
Liberman, Vladimir
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2012
Applied Physics Letters

We report a technique to measure the mid-infrared photothermal response induced by a tunable quantum cascade laser in the neat liquid crystal 4-octyl-4'-cyanobiphenyl (8CB), without any intercalated dye. Heterodyne detection using a Ti:sapphire laser of the response in the solid, smectic, nematic and isotropic liquid crystal phases allows direct detection of a weak mid-infrared normal mode absorption using an inexpensive photodetector. At high pump power in the nematic phase, we observe an interesting peak splitting in the photothermal response. Tunable lasers that can access still stronger modes will facilitate photothermal heterodyne mid-infrared vibrational spectroscopy. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4737942]

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Type
research article
DOI
10.1063/1.4737942
Author(s)
Mertiri, Alket
Jeys, Thomas
Liberman, Vladimir
Hong, M. K.
Mertz, Jerome
Altug, Hatice
Erramilli, Shyamsunder
Date Issued

2012

Published in
Applied Physics Letters
Volume

101

Issue

4

Article Number

article n°044101

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
BIOS  
Available on Infoscience
August 16, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/128627
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