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  4. Triode Solid Oxide Fuel Cell Operation Under Sulfur-Poisoning Conditions
 
conference paper

Triode Solid Oxide Fuel Cell Operation Under Sulfur-Poisoning Conditions

Caliandro, P.  
•
Diethelm, S.  
•
Van Herle, J.  
2017
Fuel Cells
12th European Solid Oxide Fuel Cell and Solid Oxide Electrolyzer (SOFC and SOE) Forum

The triode solid oxide fuel cell (SOFC) is a three electrodes configuration. The third electrode, so-called auxiliary, is connected in a way to run in electrolysis mode, while cathode and anode operate in normal fuel cell mode. This mixed operation allows to reach anode-cathode potential differences which are not accessible in normal operation. In this work, the benefits of triode operation under sulfur-poisoning conditions are shown. In particular, the difference between conventional and triode operation mode under 2ppm of H2S in H-2 are analyzed. The partial reversibility of sulfur poisoning is investigated and the observed regeneration processes are discussed for both the conventional and triode operation. After each sequence of exposure and regeneration, IV and EIS characteristics are taken. The electrochemical impedance spectra are further processed by computing the distribution of relaxation times (DRT). During triode operation, less degradation during exposure and faster stabilization after exposure and regeneration with respect to conventional operation mode are observed.

  • Details
  • Metrics
Type
conference paper
DOI
10.1002/fuce.201600196
Web of Science ID

WOS:000408318300006

Author(s)
Caliandro, P.  
Diethelm, S.  
Van Herle, J.  
Date Issued

2017

Publisher

Wiley-V C H Verlag Gmbh

Publisher place

Weinheim

Published in
Fuel Cells
Total of pages

7

Volume

17

Issue

4

Start page

457

End page

463

Subjects

Degradation

•

DRT

•

EIS

•

Sulfur-Poisoning

•

Triode SOFC

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SCI-STI-JVH  
Event nameEvent placeEvent date
12th European Solid Oxide Fuel Cell and Solid Oxide Electrolyzer (SOFC and SOE) Forum

Lucerne, SWITZERLAND

JUL 05-08, 2016

Available on Infoscience
October 9, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/141302
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