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  4. Disentangling Light- and Temperature-Induced Thermal Effects in Colloidal Au Nanoparticles
 
research article

Disentangling Light- and Temperature-Induced Thermal Effects in Colloidal Au Nanoparticles

Wang, Lijie  
•
Zare, Davood
•
Chow, Tsz Him
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February 24, 2022
Journal Of Physical Chemistry C

We present temperature-dependent (from room temperature to 80 degrees C) absorption spectra of Au/SiO2 core-shell nanoparticles (NPs) (core diameter: similar to 25 nm) in water in the range from 1.5 to 4.5 eV, which spans the localized surface plasmon resonance (LSPR) and the interband transitions. A decrease in absorption with temperature over the entire spectral range is observed, which is more prominent at the LSPR. These changes are well reproduced by theoretical calculations of the absorption spectra, based on the experimentally measured temperature-dependent real (epsilon(1)) and imaginary (epsilon(2)) parts of the dielectric constant of Au NPs and of the surrounding medium. In addition, we model the photoinduced response of the NPs over the entire spectral range. The experimental and theoretical results of the thermal heating and the simulations of the photoinduced heating are compared with the ultrafast photoinduced transient absorption (TA) spectra upon excitation of the LSPR. These show that while the latter is a reliable monitor of heating of the NP and its environment, the interband region mildly responds to heating but predominantly to the population evolution of charge carriers.

  • Details
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Type
research article
DOI
10.1021/acs.jpcc.1c10747
Web of Science ID

WOS:000766230000029

Author(s)
Wang, Lijie  
Zare, Davood
Chow, Tsz Him
Wang, Jianfang
Magnozzi, Michele
Chergui, Majed  
Date Issued

2022-02-24

Publisher

AMER CHEMICAL SOC

Published in
Journal Of Physical Chemistry C
Volume

126

Issue

7

Start page

3591

End page

3599

Subjects

Chemistry, Physical

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

surface-plasmon resonance

•

gold nanoparticles

•

metal nanoparticles

•

optical-properties

•

electron dynamics

•

vapor generation

•

heat dissipation

•

refractive-index

•

hot-electrons

•

relaxation

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSU  
Available on Infoscience
March 28, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/186687
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