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  4. Scaling Description of Dynamical Heterogeneity and Avalanches of Relaxation in Glass-Forming Liquids
 
research article

Scaling Description of Dynamical Heterogeneity and Avalanches of Relaxation in Glass-Forming Liquids

Tahaei, Ali
•
Biroli, Giulio
•
Ozawa, Misaki
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September 21, 2023
Physical Review X (PRX)

We provide a theoretical description of dynamical heterogeneities in glass-forming liquids, based on the premise that relaxation occurs via local rearrangements coupled by elasticity. In our framework, the growth of the dynamical correlation length e and of the correlation volume x4 are controlled by a zero-temperature fixed point. We connect this critical behavior to the properties of the distribution of local energy barriers at zero temperature. Our description makes a direct connection between dynamical heterogeneities and avalanche-type relaxation associated to dynamic facilitation, allowing us to relate the size distribution of heterogeneities to their time evolution. Within an avalanche, a local region relaxes multiple times; the more, the larger the avalanche. This property, related to the nature of the zero-temperature fixed point, directly leads to decoupling of particle diffusion and relaxation time (the so-called Stokes-Einstein violation). Our most salient predictions are tested and confirmed by numerical simulations of scalar and tensorial thermal elastoplastic models. Our most salient predictions are tested and confirmed by numerical simulations of scalar and tensorial thermal elasto-plastic models, and in agreement with molecular dynamic simulations.

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Type
research article
DOI
10.1103/PhysRevX.13.031034
Web of Science ID

WOS:001123011900001

Author(s)
Tahaei, Ali
Biroli, Giulio
Ozawa, Misaki
Popovi, Marko
Wyart, Matthieu  
Date Issued

2023-09-21

Publisher

American Physical Society

Published in
Physical Review X (PRX)
Volume

13

Issue

3

Article Number

031034

Subjects

Physical Sciences

•

Stokes-Einstein Relation

•

Supercooled Liquids

•

Growing Length

•

Transition

•

Behavior

•

Breakdown

•

Temperature

•

Timescales

•

Models

•

Scales

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PCSL  
FunderGrant Number

Simons Foundation

454935

SNSF

200021-165509

Available on Infoscience
February 20, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/204603
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