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  4. The Occurrence of Non-Gaussian Spectral Line Shapes of Molecules in Electrostatically Disordered Media
 
research article

The Occurrence of Non-Gaussian Spectral Line Shapes of Molecules in Electrostatically Disordered Media

Van Mourik, Frank  
•
Chergui, Majed  
•
van der Zwan, Gert
2001
The Journal of Physical Chemistry B

We calc. the effects of relatively strong elec. fields, corresponding to typical values for the fields inside glasses and proteins, on the spectroscopic properties of a simple two-level mol. Disorder in the elec. field strength is employed as a phys. source for inhomogeneous broadening. A striking result is that a Gaussian probability distribution for the field over the ensemble does not give rise to a Gaussian spectral line shape. The results are used to describe the absorption spectra of the B800 band of the B800-850 light-harvesting complex of photosynthetic purple bacteria. [on SciFinder (R)]

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Type
research article
DOI
10.1021/jp011601v
Author(s)
Van Mourik, Frank  
Chergui, Majed  
van der Zwan, Gert
Date Issued

2001

Published in
The Journal of Physical Chemistry B
Volume

105

Issue

40

Start page

9715

End page

9718

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSU  
Available on Infoscience
February 27, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/225804
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