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research article

Controlling conjugated polymer morphology and charge carrier transport with a flexible-linker approach

Gasperini, A.  
•
Bivaud, S.  
•
Sivula, K.  
2014
Chemical Science

The Stille-coupling polymerization of a short conjugated polymer with an aliphatic linker was used to demonstrate a prototype in a new class of polymer semiconductors wherein the conjugation segment length and the length of the entire chain can be independently controlled. Subsequent thermal, morphological, and 2D grazing-incidence crystallographic analysis revealed this prototype polymer's ability to exhibit distinct thin-film morphologies without changing the molecular weight. In field-effect transistors this unique ability gave rise to an improvement of the charge carrier mobility from fibril-type (0.01 cm(2) V-1 s(-1)) to terrace morphologies (0.04 cm(2) V-1 s(-1)). When compared to a fully-conjugated, high molecular weight polymer, these differences afforded insight into the roles of inter-and intramolecular charge transport in the film, highlighting the importance of chain self-assembly on charge transport. Overall, our results indicate that employing linkers is a promising route to advance morphology control in semiconducting polymer based devices.

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Type
research article
DOI
10.1039/C4SC02073A
Web of Science ID

WOS:000344376400047

Author(s)
Gasperini, A.  
Bivaud, S.  
Sivula, K.  
Date Issued

2014

Publisher

Royal Soc Chemistry

Published in
Chemical Science
Volume

5

Issue

12

Start page

4922

End page

4927

Subjects

thin-film transistors

•

field-effect mobility

•

molecular-weight

•

Polymer semiconductor

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LIMNO  
Available on Infoscience
October 21, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/107517
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