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research article

Intrinsic and interfacial kinetics of perovskite solar cells under photo and bias-induced degradation and recovery

Yadav, Pankaj
•
Prochowicz, Daniel  
•
Alharbi, Essa A.  
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2017
Journal Of Materials Chemistry C

Perovskite solar cells (PSCs) have emerged as a potential candidate for high efficiency low-cost photovoltaic technology. However, the intrinsic and interfacial responses of PSCs under photo and bias-induced degradation and recovery have not been clearly understood. Herein, the influence of illumination and bias on the intrinsic and interfacial characteristics of PSCs is examined by studying the role of trap states, perovskite dielectric relaxation phenomena, transport and recombination characteristics as well as ion movements. We found that under illumination and bias stress conditions, the photo-current at short circuit conditions was decreased in a reversible way and recovered to its initial value after keeping the device in the dark. On the basis of electrical measurements and analysis, we conclude that the full recovery of PSC performance was limited by an increase in the relative dielectric constant, series and shunt resistances and enhanced recombination pathways under stimuli conditions.

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Type
research article
DOI
10.1039/c7tc02652h
Web of Science ID

WOS:000407338200015

Author(s)
Yadav, Pankaj
Prochowicz, Daniel  
Alharbi, Essa A.  
Zakeeruddin, Shaik M.  
Gratzel, Michael  
Date Issued

2017

Publisher

Royal Soc Chemistry

Published in
Journal Of Materials Chemistry C
Volume

5

Issue

31

Start page

7799

End page

7805

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
September 5, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/140072
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