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  4. Article Organic-inorganic hybrid nature enables efficient and stable CsPbI3-based perovskite solar cells
 
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Article Organic-inorganic hybrid nature enables efficient and stable CsPbI3-based perovskite solar cells

Jiang, Yang
•
Xu, Tian-Fei
•
Du, Hong-Qiang
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December 20, 2023
Joule

CsPbI3-based perovskite solar cells (PSCs) have attracted intense research interest since the inorganic absorber layer has better thermal stability compared with hybrid perovskites. However, CsPbI3 suffers from structural instability due to an easily induced phase transition from the photoactive phase to the photoinactive phase. Introducing (CH3)(2)NH2I (dimethylammonium iodide [DMAI]) into the CsPbI3 precursor solution stabilizes the tetragonal (beta-phase) of CsPbI3, but there is still debate about whether DMA(+) is incorporated in the perovskite structure. Here, we report unambiguous evidence for the formation of tetragonal (beta-) (DMA, Cs)PbI3 by substituting the small ionic radius Cs+ with the large organic cation DMA(+). The organic-inorganic hybrid beta-(DMA, Cs)PbI3 shows a better optoelectronic properties than inorganic orthorhombic (gamma-phase) CsPbI3. Consequently, PSCs based on beta-(DMA, Cs)PbI3 exhibit a champion power conversion efficiency of 19.76%. These observations suggest that hybrid beta-(DMA, Cs)PbI3, with a dominant inorganic composition, is preferable compared with inorganic gamma-CsPbI3 for efficient and stable PSCs.

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Type
research article
DOI
10.1016/j.joule.2023.10.019
Web of Science ID

WOS:001143799500001

Author(s)
Jiang, Yang
Xu, Tian-Fei
Du, Hong-Qiang
Rothmann, Mathias Uller
Yin, Zhi-Wen
Yuan, Ye
Xiang, Wan-Chun
Hu, Zhi-Yi
Liang, Gui-Jie
Liu, Sheng-Zhong
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Date Issued

2023-12-20

Publisher

Cell Press

Published in
Joule
Volume

7

Issue

12

Subjects

Physical Sciences

•

Technology

•

Crystallization

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GMF  
FunderGrant Number

National Natural Science Foundation of China (NSFC)

Nature Science Foundation of Hubei province

51972255

Fundamental Research Funds for the Central Universities (WUT)

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Available on Infoscience
February 23, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/205301
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