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  4. Nanocavities for Molecular Optomechanics: Their Fundamental Description and Applications
 
review article

Nanocavities for Molecular Optomechanics: Their Fundamental Description and Applications

Roelli, Philippe
•
Hu, Huatian
•
Verhagen, Ewold
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November 6, 2024
ACS Photonics

Vibrational Raman scattering-a process where light exchanges energy with a molecular vibration through inelastic scattering-is most fundamentally described in a quantum framework where both light and vibration are quantized. When the Raman scatterer is embedded inside a plasmonic nanocavity, as in some sufficiently controlled implementations of surface-enhanced Raman scattering (SERS), the coupled system realizes an optomechanical cavity where coherent and parametrically amplified light-vibration interaction becomes a resource for vibrational state engineering and nanoscale nonlinear optics. The purpose of this Perspective is to clarify the connection between the languages and parameters used in the fields of molecular cavity optomechanics (McOM) versus its conventional, "macroscopic" counterpart and to summarize the main results achieved so far in McOM and the most pressing experimental and theoretical challenges. We aim to make the theoretical framework of molecular cavity optomechanics practically usable for the SERS and nanoplasmonics community at large. While quality factors (Q) and mode volumes (V) essentially describe the performance of a nanocavity in enhancing light-matter interaction, we point to the light-cavity coupling efficiencies (eta) and optomechanical cooperativities ( C ) as the key parameters for molecular optomechanics. As an illustration of the significance of these quantities, we investigate the feasibility of observing optomechanically induced transparency with a molecular vibration-a measurement that would allow for a direct estimate of the optomechanical cooperativity.

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Type
review article
DOI
10.1021/acsphotonics.4c01548
Web of Science ID

WOS:001350027600001

PubMed ID

39584033

Author(s)
Roelli, Philippe

CIC NanoGUNE BRTA

Hu, Huatian

Istituto Italiano di Tecnologia - IIT

Verhagen, Ewold

AMOLF

Reich, Stephanie

Free University of Berlin

Galland, Christophe  

École Polytechnique Fédérale de Lausanne

Date Issued

2024-11-06

Publisher

AMER CHEMICAL SOC

Published in
ACS Photonics
Volume

11

Issue

11

Subjects

Plasmonic antennas

•

Surface-enhanced Raman scattering

•

Cavity optomechanics

•

Molecular vibrations

•

Raman spectroscopy

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LASPE  
FunderFunding(s)Grant NumberGrant URL

Horizon 2020

Netherlands Organization for Scientific Research (NWO)

829067;820196

Horizon 2020

214993;198898

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Available on Infoscience
January 28, 2025
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/245731
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