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research article

Photoelectrochemical Tandem Cells for Solar Water Splitting

Prévot, Mathieu S.
•
Sivula, Kevin  
2013
Journal Of Physical Chemistry C

In order to be economically competitive with simple "brute force" (i.e., PV + electrolyzer) strategies or the production of promising solar fuels, like H-2, from fossil fuels, a practical photoelectrochemical device must optimize cost, longevity, and performance. A promising approach that meets these requirements is the combination of stable and inexpensive oxide semiconductor electrodes in a tandem photoelectrochemical device. In this article, we give an overview of the field including an examination of the potential solar-to-fuel conversion efficiency expected in a device with realistic losses. We next discuss recent advances with increasing the performance of promising semiconductor electrode materials and highlight how these advances have led to state-of-the-art solar-to-chemical efficiencies in the 2-3% range in real devices. Challenges for further optimization are further outlined.

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Type
research article
DOI
10.1021/jp405291g
Web of Science ID

WOS:000330162800001

Author(s)
Prévot, Mathieu S.
Sivula, Kevin  
Date Issued

2013

Publisher

American Chemical Society

Published in
Journal Of Physical Chemistry C
Volume

117

Issue

35

Start page

17879

End page

17893

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LIMNO  
Available on Infoscience
June 2, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/103843
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