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  4. Intrinsic or nucleation-driven switching: An insight from nanoscopic analysis of negative capacitance Hf1-xZrxO2-based structures
 
research article

Intrinsic or nucleation-driven switching: An insight from nanoscopic analysis of negative capacitance Hf1-xZrxO2-based structures

Stolichnov, I  
•
Cavalieri, M.
•
Gastaldi, C.
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October 26, 2020
Applied Physics Letters

HfO2-based ferroelectrics have dramatically changed the application perspectives of polarization-switching materials for information processing and storage. Their CMOS compatibility and preservation of high reversible polarization down to a few nanometer thickness make them attractive for various device concepts including non-volatile memories and negative-capacitance-enhanced steep-slope transistors. In the context of these applications, the long-standing discussion of intrinsic (thermodynamic) or extrinsic nuclei-limited switching (NLS) in ferroelectrics has recently gained importance. In particular, the negative capacitance effect that is formally described by the Landau-Ginzburg-Devonshire formalism implies the intrinsic polarization switching driven by the thermodynamic coercive field. On the other hand, recent studies reported the nucleation-limited extrinsic switching, which does not result in the hysteresis-free negative capacitance effect. Here, we analyze the polarization response in the nanometer scale on the ferroelectric/dielectric bilayer where the negative capacitance has been previously demonstrated. Our analysis of the two limiting cases of quasi-static switching and the earlier reported ultra-fast polarization response supports the intrinsic polarization reversal scenario. The compatibility of this mechanism with the previously reported NLS region-by-region switching with remarkably low domain wall velocity is addressed. Our results confirm the usability of CMOS-compatible polycrystalline HZO ferroelectric films for gates operating in the negative-capacitance regime. Furthermore, they point towards possible solutions for optimizing their switching properties for applications including memories.

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Type
research article
DOI
10.1063/5.0021272
Web of Science ID

WOS:000591637300002

Author(s)
Stolichnov, I  
•
Cavalieri, M.
•
Gastaldi, C.
•
Hoffmann, M.
•
Schroeder, U.
•
Mikolajick, T.
•
Ionescu, A. M.  
Date Issued

2020-10-26

Publisher

AMER INST PHYSICS

Published in
Applied Physics Letters
Volume

117

Issue

17

Article Number

172902

Subjects

Physics, Applied

•

Physics

•

performance

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
NANOLAB  
Available on Infoscience
December 9, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/173935
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