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  4. Convergent Synthesis of Near-Infrared Absorbing, "Push-Pull", Bisthiophene-Substituted, Zinc(II) Phthalocyanines and their Application in Dye-Sensitized Solar Cells
 
research article

Convergent Synthesis of Near-Infrared Absorbing, "Push-Pull", Bisthiophene-Substituted, Zinc(II) Phthalocyanines and their Application in Dye-Sensitized Solar Cells

Ince, Mine
•
Cardinali, Francois
•
Yum, Jun-Ho  
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2012
Chemistry - A European Journal

Zinc(II) phthalocyanine dyes that contain triarylamine-terminated bisthiophene and hexylbisthiophene groups have been synthesized by a convergent approach by using carboxytriiodoZnPc as a precursor. Further transformation of the iodo groups by a Pd-catalyzed reaction allowed easy preparation of further extended p-conjugated carboxyZnPcs. These dyes have been used as sensitizers in dye-sensitized solar cells, which exhibit a panchromatic response and moderate overall efficiencies.

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Type
research article
DOI
10.1002/chem.201200020
Web of Science ID

WOS:000303497600029

Author(s)
Ince, Mine
Cardinali, Francois
Yum, Jun-Ho  
Victoria Martinez-Diaz, M.
Nazeeruddin, Mohammad K.  
Graetzel, Michael  
Torres, Tomas
Date Issued

2012

Published in
Chemistry - A European Journal
Volume

18

Start page

6343

End page

6348

Subjects

bisthiophene

•

dye-sensitized solar cells

•

near-infrared dyes

•

phthalocyanines

•

Nanocrystalline Tio2 Films

•

Photovoltaic Cells

•

Redox Electrolyte

•

Efficiency

•

Porphyrins

•

Conversion

•

System

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
June 1, 2012
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/81248
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