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research article

Transforming Hybrid Organic Inorganic Perovskites by Rapid Halide Exchange

Pellet, Norman  
•
Teuscher, Joel  
•
Maier, Joachim
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2015
Chemistry Of Materials

We report on rapid halide exchange in metal halide perovskite of the general formula MAPbX(3) (X = Cl, Br, or I). We find that when the perovskite is infiltrated in a mesoscopic scaffold, halide substitution on the perovskite lattice is strikingly fast, being completed within seconds or minutes after contact with the halide solution. An exception is the exchange of bromide by iodide, which is slower and incomplete. Halide substitution occurs rapidly even for planar perovskite films which are several tens of nanometers thick. However, with thicker films the reaction requires hours, showing that the mesoscale greatly accelerates the halide exchange process. The time course of the substitution reactions has been monitored by in situ photoluminescence, absorption spectroscopy, and X-ray diffraction measurements. We show that the halide exchange can be a powerful tool to effect perovskite transformations.

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Type
research article
DOI
10.1021/acs.chemmater.5b00281
Web of Science ID

WOS:000351971600036

Author(s)
Pellet, Norman  
Teuscher, Joel  
Maier, Joachim
Graetzel, Michael  
Date Issued

2015

Publisher

American Chemical Society

Published in
Chemistry Of Materials
Volume

27

Issue

6

Start page

2181

End page

2188

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
May 29, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/114405
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