Complex viscosity of polyhyaluronic acid
We use the macromolecular moments method of Chakraborty et al. [Phys Fluids, 34, 093109 (2022)] to calculate the complex viscosity of an aqueous suspension of polyhyaluronic acid. We do so by first calculating the equilibrium structure of the macromolecule, which leads us to its principal moments of inertia. Inserting these moments into the main results of general rigid bead-rod theory, yields from first principles, the complex viscosity of an aqueous suspension of polyhyaluronic acid. For polyhyaluronic, we find that one bead of a shish-kebab corresponds to one monomer of polyhyaluronic. Comparing our results with published complex viscosity measurements on polyhyaluronic acid suspensions, uncovers good agreement, and even better agreement with hydrodynamic interaction.
WOS:001441552700014
University of Ottawa
Massachusetts Institute of Technology (MIT)
École Polytechnique Fédérale de Lausanne
Peking University
2025-03-01
37
3
033116
REVIEWED
EPFL
| Funder | Funding(s) | Grant Number | Grant URL |
Natural Sciences and Engineering Research Council of Canada10.13039/501100000038 | |||
Natural Sciences and Engineering Research Council of Canada (NSERC) | |||
Natural Sciences and Engineering Research Council of Canada (NSERC) | |||
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