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  4. Understanding the rate-dependent J-V hysteresis, slow time component, and aging in CH3NH3PbI3 perovskite solar cells: the role of a compensated electric field
 
research article

Understanding the rate-dependent J-V hysteresis, slow time component, and aging in CH3NH3PbI3 perovskite solar cells: the role of a compensated electric field

Tress, W.  
•
Marinova, N.  
•
Moehl, T.  
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2015
Energy & Environmental Science

In this work we show that the rate-dependent hysteresis seen in current-voltage scans of CH3NH3PbI3 perovskite solar cells is related to a slow field-induced process that tends to cancel the electric field in the device at each applied bias voltage. It is attributed to the build-up of space charge close to the contacts, independent of illumination and most likely due to ionic displacement, which is enhanced when the device undergoes aging. This process can also lead to a reduction of the open-circuit voltage or the steady-state photocurrent and does not directly correlate with the development of the hysteresis if it is measured at a fixed voltage sweep rate.

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Type
research article
DOI
10.1039/c4ee03664f
Web of Science ID

WOS:000352274600025

Author(s)
Tress, W.  
Marinova, N.  
Moehl, T.  
Zakeeruddin, S. M.  
Nazeeruddin, Mohammad Khaja  
Graetzel, M.  
Date Issued

2015

Publisher

Royal Soc Chemistry

Published in
Energy & Environmental Science
Volume

8

Issue

3

Start page

995

End page

1004

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GMF  
LPI  
Available on Infoscience
May 29, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/114775
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