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research article

Rydberg-valence perturbations in matrix-isolated nitric oxide

Chergui, Majed  
•
Schwentner, Nikolaus
1992
The Journal of Chemical Physics

The absorption spectrum of NO in rare gas matrixes was restudied. The valence B2P(v',0) bands which, in the gas phase, show perturbations for v'>=7 due to homogeneous configuration mixing with the Rydberg C2P state, appear unperturbed up to v' = 10 in Xe, 12 in Kr, 14 in Ar, and 19 in Ne matrixes. The perturbations are shifted to higher energies due to the large blue matrix shifts experienced by the Rydberg states. They appear as irregular vibrational spacings, anomalous intensities, and modifications of the B2P(v',0) band profiles. The intensity patterns are qual. explained in terms of quantum-mech. interference effects. When resonant with a multiphoton Rydberg band, Fano line shapes appear in place of the sharp B(v',0) valence lines. The line shapes were simulated by the Fano theory assuming that only part of the Rydberg multiphonon quasicontinuum interferes with the sharp valence band. Good agreement is obtained with the exptl. spectrum and the fitted Fano indexes lie close to the calcd. ones. [on SciFinder (R)]

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Type
research article
DOI
10.1063/1.463958
Author(s)
Chergui, Majed  
Schwentner, Nikolaus
Date Issued

1992

Published in
The Journal of Chemical Physics
Volume

97

Issue

5

Start page

2881

End page

90

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSU  
Available on Infoscience
February 27, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/225737
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