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research article

Rheological behavior of hyperbranched polymer/montmorillonite clay nanocomposites

Rodlert, M.  
•
Plummer, C. J. G.  
•
Leterrier, Y.  
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2004
Journal of Rheology

The equilibrium rheological properties of a range of isotropic exfoliated and intercalated hyperbranched polymer (HBP)/montmorillonite (MMT) clay nanocomposites have been investigated using low strain oscillating shear measurements at temperatures above the glass transition temperature of the HBP. Predominantly exfoliated nanocomposites showed a sharp increase in shear viscosity at about 0.8 wt % MMT, associated with a transition from Newtonian to solid-like behavior, which was characterized in terms of a limiting shear modulus at low frequencies and a limiting viscosity at high frequencies, both of which were strongly dependent on the MMT content. Intercalated HBP/organically modified MMT nanocomposites showed qualitatively similar behavior, but the increase in viscosity with MMT content was far weaker. This was argued to reflect a significantly lower effective particle aspect ratio than in the exfoliated nanocomposites.

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Type
research article
DOI
10.1122/1.1773780
Web of Science ID

WOS:000224112300006

Author(s)
Rodlert, M.  
Plummer, C. J. G.  
Leterrier, Y.  
Månson, J.-A. E.  
Grünbauer, H. J. M.
Date Issued

2004

Published in
Journal of Rheology
Volume

48

Issue

5

Start page

1049

End page

1065

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LTC  
Available on Infoscience
June 26, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/232358
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