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research article

Direct Ink Writing of Rigid Microparticles

Pradal, Pauline  
•
Kim, Jong Bin
•
Nam, Seong Kyeong
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January 15, 2025
Small

Direct ink writing (DIW) enables 3D printing of macroscopic objects with well-defined structures and compositions that controllably change over length scales of order 100 µm. Unfortunately, only a limited number of materials can be processed through DIW because it imparts stringent rheological requirements on inks. This limitation can be overcome for soft materials, if they are formulated as microparticles that, if jammed, fulfill the rheological requirements to be printed. By contrast, densely packed rigid microparticles with stiffnesses exceeding 2 MPa do not exhibit appropriate rheological properties that enable DIW. Here, an ink composed of up to 60 vol% rigid microparticles with core stiffnesses up to 50 MPa is introduced. To achieve this goal, rigid microparticles possessing soft hydrogel shells are produced. The 3D printed fragile granular structure is transformed into a load-bearing granular material through the formation of a 2nd network within the soft shells and in the interstitial spaces. The potential of these particles is demonstrated to be printed into intricate 3D structures, such as a trophy cup, or cast into flexible macroscopic photonic films.

  • Details
  • Metrics
Type
research article
DOI
10.1002/smll.202405675
Scopus ID

2-s2.0-85209756611

Author(s)
Pradal, Pauline  

École Polytechnique Fédérale de Lausanne

Kim, Jong Bin

School of Engineering and Applied Science

Nam, Seong Kyeong

Korea Advanced Institute of Science and Technology

Kim, Shin Hyun

Korea Advanced Institute of Science and Technology

Amstad, Esther  

École Polytechnique Fédérale de Lausanne

Date Issued

2025-01-15

Published in
Small
Volume

21

Issue

2

Article Number

2405675

Subjects

3D printing

•

colloidal self-assembly

•

mechanics

•

microfluidics

•

rheology

•

stiff microparticles

•

structural colors

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SMAL  
FunderFunding(s)Grant NumberGrant URL

SNSF

IZKSZ2_188333

Available on Infoscience
January 25, 2025
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/244140
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