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research article

Photon echo peak shift experiments in the UV: p-terphenyl in different solvents

Ajdarzadeh Oskouei, A.  
•
Braem, O.  
•
Cannizzo, A.  
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2008
Journal of Molecular Liquids

We present a new photon echo set-up operating in the UV range and our 1st results of photon echo peak shift (PEPS) expts. of a small non-polar dye mol., p-terphenyl (pTP), in 3 different solvents: EtOH, MeOH, and 2-propanol. The expts. show the feasibility of UV transient grating and photon echo measurements and highlight the sensitivity of this technique for the study of non-polar solvation dynamics. The transient grating expts. indicate a relaxation of the ground state hole of about 6 ps. The photon echo expts. show that while electronic dephasing occurs on timescales <100 fs, solvation dynamics timescales are in the picosecond regime, in agreement with the literature.

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Type
research article
DOI
10.1016/j.molliq.2008.01.015
Web of Science ID

WOS:000259267200004

Author(s)
Ajdarzadeh Oskouei, A.  
Braem, O.  
Cannizzo, A.  
van Mourik, F.  
Tortschanoff, A.  
Chergui, M.  
Date Issued

2008

Published in
Journal of Molecular Liquids
Volume

141

Issue

3

Start page

118

End page

123

Subjects

Photon echo; Solvent effect (photon echo peak shift expts. in UV of p-terphenyl in different solvents)

•

Sterphenyl photon echo peak shift solvent effect

Note

CAN 149:481043

73-2

Optical, Electron, and Mass Spectroscopy and Other Related Properties

Laboratoire de Spectroscopie Ultrarapide, ISIC, FSB, BSP,Ecole Polytechnique Federale de Lausanne (EPFL),Lausanne,Switz.

Journal

written in English.

92-94-4 (p-Terphenyl) Role: PEP (Physical, engineering or chemical process), PRP (Properties), PROC (Process) (photon echo peak shift expts. in UV of p-terphenyl in different solvents)

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSU  
Available on Infoscience
March 18, 2009
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/36201
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