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research article

Monolithic perovskite/silicon-heterojunction tandem solar cells processed at low temperature

Albrecht, Steve
•
Saliba, Michael  
•
Baena, Juan Pablo Correa  
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2016
Energy & Environmental Science

Tandem solar cells combining silicon and perovskite absorbers have the potential to outperform state-of-the-art high efficiency silicon single junction devices. However, the practical fabrication of monolithic silicon/perovskite tandem solar cells is challenging as material properties and processing requirements such as temperature restrict the device design. Here, we fabricate an 18% efficient monolithic tandem cell formed by a silicon heterojunction bottom-and a perovskite top-cell enabling a very high open circuit voltage of 1.78 V. The monolithic integration was realized via low temperature processing of the semitransparent perovskite sub-cell where an energetically aligned electron selective contact was fabricated by atomic layer deposition of tin oxide. The hole selective, transparent top contact was formed by a stack of the organic hole transport material spiro-OMeTAD, molybdenum oxide and sputtered indium tin oxide. The tandem cell design is currently limited by the photo-current generated in the silicon bottom cell that is reduced due to reflectance losses. Based on optical modelling and first experiments, we show that these losses can be significantly reduced by combining optical optimization of the device architecture including light trapping approaches.

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Type
research article
DOI
10.1039/c5ee02965a
Web of Science ID

WOS:000367622700006

Author(s)
Albrecht, Steve
Saliba, Michael  
Baena, Juan Pablo Correa  
Lang, Felix
Kegelmann, Lukas
Mews, Mathias
Steier, Ludmilla  
Abate, Antonio  
Rappich, Joerg
Korte, Lars
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Date Issued

2016

Publisher

Royal Soc Chemistry

Published in
Energy & Environmental Science
Volume

9

Issue

1

Start page

81

End page

88

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

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LPI  
LSPM  
GMF  
Available on Infoscience
February 16, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/123805
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