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research article

Nitrate removal and young stream water fractions at the catchment scale

Benettin, Paolo  
•
Fovet, Ophelie
•
Li, Li
May 5, 2020
Hydrological Processes

Despite extensive research on nitrate export and removal, nutrient contamination remains a major threat to water bodies worldwide. At the local scale, nitrate removal is governed by biogeochemical conditions that vary in space and time, making integration to entire landscapes critical. Water transit times have often been used to describe solute transport, but the relation between water age and nitrate removal at the catchment scale is still poorly understood. We test the hypothesis that nitrate removal peaks when the fraction of young water in discharge is at its minimum, because nitrate removal occurs mostly under dry conditions where deeper, older groundwater dominates streamflow. We tested this hypothesis by exploring a detailed water quality record from the Kervidy-Naizin catchment (FR) and comparing the dynamics of nitrate to those of a conservative solute (chloride). We find that estimates of nitrate removal are consistent with previous estimates at the site and they show a good (inverse) correlation with the fraction of streamflow that is younger than 2.5 months. However, this young water fraction cannot be used to predict nitrate removal in the winter-spring period, when no removal is observed regardless of streamflow age. While this leads us to reject our hypothesis during the winter period, it also suggests that water age distributions and their correlation with nitrate removal can possibly reveal distinct sources of stream water at different hydrologic regimes and relevant biogeochemical reactions.

  • Details
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Type
research article
DOI
10.1002/hyp.13781
Web of Science ID

WOS:000530357700001

Author(s)
Benettin, Paolo  
Fovet, Ophelie
Li, Li
Date Issued

2020-05-05

Publisher

WILEY

Published in
Hydrological Processes
Volume

34

Issue

12

Start page

2725

End page

2738

Subjects

Water Resources

•

Water Resources

•

agricultural catchment

•

chloride transport

•

denitrification

•

naizin

•

nitrate removal

•

sas function

•

water age

•

young water fraction

•

mean transit times

•

high-frequency

•

environmental systems

•

weathering rates

•

residence time

•

organic-carbon

•

nitrogen

•

dynamics

•

denitrification

•

groundwater

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
ECHO  
Available on Infoscience
May 14, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/168737
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