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research article

Aggregates of plasmonic nanoparticles for broadband light trapping in dye-sensitized solar cells

Sharifi, Nafiseh
•
Dabirian, Ali  
•
Danaei, Davood
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2016
Journal Of Optics

Metallic nanoparticles (NPs) have not been effective in improving the overall performance of the cells with micrometer-thick absorbing layers mainly due to the parasitic optical dissipation in the metal. Here, using both experiment and theory, we demonstrate that aggregates of metallic NPs enhance the light absorption of dye-sensitized solar cells of a few micrometer-thick light absorbing layers. The composite electrode containing the optimal concentration of 5 wt% Au@SiO2 aggregates shows the enhancement of 80% and 52% in external quantum efficiency and photocurrent density, respectively. The superior performance of the aggregates relative to NP is attributed to their larger scattering efficiency using full-wave optical simulations. This is further confirmed by optical spectroscopic measurements showing that a large fraction of the incident light couples into the diffused components because of the presence of these metallic aggregates. The optical absorption enhancement is broadband and it is particularly strong at wavelengths larger than 680 nm where the optical absorption of dye molecules is weak.

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Type
research article
DOI
10.1088/2040-8978/18/1/015902
Web of Science ID

WOS:000367187000051

Author(s)
Sharifi, Nafiseh
Dabirian, Ali  
Danaei, Davood
Taghavinia, Nima
Date Issued

2016

Publisher

Iop Publishing Ltd

Published in
Journal Of Optics
Volume

18

Issue

1

Article Number

015902

Subjects

plasmonic nanoparticles

•

scattered-field

•

light scattering

•

aggregates

•

dye-sensitized solar cells

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

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PV-LAB  
Available on Infoscience
February 16, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/123834
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