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  4. Routes for Efficiency Enhancement in Fluorescent TADF Exciplex Host OLEDs Gained from an Electro-Optical Device Model
 
research article

Routes for Efficiency Enhancement in Fluorescent TADF Exciplex Host OLEDs Gained from an Electro-Optical Device Model

Regnat, Markus
•
Pernstich, Kurt P.
•
Kim, Kwon-Hyeon
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February 1, 2020
Advanced Electronic Materials

Fluorescence-based organic light-emitting diodes (OLEDs) using thermally activated delayed fluorescence (TADF) have increasingly attracted attention in research and industry. One method to implement TADF is based on an emitter layer composed of an exciplex host and a fluorescent dopant. Even though the experimental realization of this concept has demonstrated promising external quantum efficiencies, the full potential of this approach has not yet been assessed. To this end, a comprehensive electro-optical device model accounting for the full exciton dynamics including triplet harvesting and exciton quenching is presented. The model parameters are fitted to multiple output characteristics of an OLED comprising a TADF exciplex host with a fluorescent emitter, showing an external quantum efficiency of >10%. With the model at hand, an emission zone analysis and a parameter study are performed, and possible routes for further efficiency enhancement are presented.

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Type
research article
DOI
10.1002/aelm.201900804
Web of Science ID

WOS:000514635800005

Author(s)
Regnat, Markus
Pernstich, Kurt P.
Kim, Kwon-Hyeon
Kim, Jang-Joo
Nueesch, Frank  
Ruhstaller, Beat
Date Issued

2020-02-01

Publisher

WILEY

Published in
Advanced Electronic Materials
Volume

6

Issue

2

Article Number

1900804

Subjects

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Physics, Applied

•

Science & Technology - Other Topics

•

Materials Science

•

Physics

•

electro-optical simulations

•

exciton dynamics

•

split emission zones

•

triplet harvesting

•

triplet-triplet annihilation

•

light-emitting-diodes

•

profile

•

zone

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
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Available on Infoscience
March 14, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/167281
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