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  4. Hybridization and electron-phonon coupling in ferroelectric BaTiO3 probed by resonant inelastic x-ray scattering
 
research article

Hybridization and electron-phonon coupling in ferroelectric BaTiO3 probed by resonant inelastic x-ray scattering

Fatale, Sara  
•
Moser, Simon  
•
Miyawaki, Jun
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2016
Physical Review B

We investigated the ferroelectric perovskite material BaTiO3 by resonant inelastic x-ray scattering (RIXS) at the Ti L-3 edge. We observe with decreasing temperature a transfer of spectral weight from the elastic to the charge-transfer spectral features, indicative of increasing Ti 3d-O 2p hybridization. When the incident photon energy selects transitions to the Ti 3d e(g) manifold, the quasielastic RIXS response exhibits a tail indicative of phonon excitations. A fit of the spectral line shape by a theoretical model allows us to estimate the electron-phonon coupling strength M similar to 0.25 eV, which places BaTiO3 in the intermediate coupling regime.

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Type
research article
DOI
10.1103/PhysRevB.94.195131
Web of Science ID

WOS:000387890700002

Author(s)
Fatale, Sara  
•
Moser, Simon  
•
Miyawaki, Jun
•
Harada, Yoshihisa
•
Grioni, Marco  
Date Issued

2016

Publisher

Amer Physical Soc

Published in
Physical Review B
Volume

94

Issue

19

Article Number

195131

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSE  
Available on Infoscience
January 24, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/133638
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