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  4. Manufacturing of zirconia microspheres doped with erbia, yttria and ceria by internal gelation process as a part of a cermet fuel
 
research article

Manufacturing of zirconia microspheres doped with erbia, yttria and ceria by internal gelation process as a part of a cermet fuel

Idemitsu, Kazuya
•
Arima, Tatsumi
•
Inagaki, Yaohiro
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2003
Journal of Nuclear Materials

Zirconium oxide is an inert matrix candidate for the transmutation of plutonium in light water reactor (LWR). The thermal conductivity of cubic zirconia is however lower than the conductivities of UO2 and MOX. Special designs are therefore necessary to avoid high peaking temperatures close to the melting point in the zirconia pellet. Cermet would be a favorable design to improve the thermal conductivity. The suggested cermet fuel consists of fine plutonium doped stabilized zirconia particles dispersed in a metallic inert matrix. Manufacturing tests on cubic zirconia microspheres were carried out by using the internal gelation process developed at the Paul Scherrer Institute. Gelation was conducted successfully and the sintered spheres had a homogeneous single cubic structure. The lattice parameter of the cubic zirconia was estimated as a function of the Er, Y and Ce atomic fraction using a simplified semi-quantitative formula. On the experimental side, it is necessary to further investigate the ideal fabrication conditions, because some gel spheres were opaque and fragile and most of the sintered spheres were cracked, nicked and porous.

  • Details
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Type
research article
DOI
10.1016/S0022-3115(03)00130-2
Author(s)
Idemitsu, Kazuya
Arima, Tatsumi
Inagaki, Yaohiro
Torikai, Satoshi
Pouchon, Manuel A.  
Date Issued

2003

Publisher

Elsevier

Published in
Journal of Nuclear Materials
Volume

319

Start page

31

End page

36

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LNM_PSI  
Available on Infoscience
April 15, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/113371
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