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research article

Solution-Processed Organic Optical Upconversion Device

Strassel, Karen
•
Ramanandan, Santhanu Panikar
•
Abdolhosseinzadeh, Sina
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July 3, 2019
ACS Applied Materials & Interfaces

Imaging in the near-infrared (NIR) is getting increasingly important for applications such as machine vision or medical imaging. NIR-to-visible optical upconverters consist of a monolithic stack of a NIR photodetector and a visible light-emitting unit. Such devices convert NIR light directly to visible light and allow capturing a NIR image with an ordinary camera. Here, five-layer organic solution-processed upconverters (OUCs) are reported which consist of a squaraine dye NIR photodetector and a fluorescent poly(para-phenylene vinylene) copolymer (super yellow)-based organic light-emitting diode (OLED) or light-emitting electrochemical cell (LEC), respectively. Both OLED-OUCs and LEC-OUCs convert NIR light at 980 nm to yellow light at around 575 nm with comparable device metrics of performance, such as a turn-on voltage of 2.7-2.9 V and a NIR-to-visible photon conversion efficiency of around 1.6%. Because of the presence of a salt in the emitting layer, the LEC OUC is a temporally dynamic device. The LEC OUC turn-on and relaxation behavior is characterized in detail. It is demonstrated that a particular ionic distribution and thereby the LEC OUC status can be frozen by storing the device in the presence of a small voltage applied. This provides a test chart for quantitative measurements.

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Type
research article
DOI
10.1021/acsami.9b06732
Web of Science ID

WOS:000474670100058

Author(s)
Strassel, Karen
Ramanandan, Santhanu Panikar
Abdolhosseinzadeh, Sina
Diethelm, Matthias
Nuesch, Frank  
Hany, Roland
Date Issued

2019-07-03

Publisher

AMER CHEMICAL SOC

Published in
ACS Applied Materials & Interfaces
Volume

11

Issue

26

Start page

23428

End page

23435

Subjects

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Science & Technology - Other Topics

•

Materials Science

•

upconverter

•

photodetector

•

near-infrared

•

squaraine

•

light-emitting electrochemical cell

•

emitting electrochemical-cells

•

efficiency

•

diodes

•

layer

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LOMM  
Available on Infoscience
July 24, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/159332
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