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research article

New metric for carrier selective contacts for silicon heterojunction solar cells

Sharma, Rupendra Kumar
•
Boccard, Mathieu  
•
Holovsky, Jakub  
September 15, 2022
Solar Energy

Heterojunction carrier selective contacts for solar cells have gained great attention because of the ability of these contacts to efficiently collect majority carriers while hindering the recombination of minority carriers, thus resulting in the highest reported voltage among crystalline silicon technologies. The electrode work-function, doping and thickness of the doped layer remain the key parameters for governing the cell performance. Recently, we have studied the requirements for carrier selective contacts under various illumination levels and reported logarithmic dependence of these parameters. In this work, we define a new metric for describing the ability of a contact to collect the carriers and named it as contact strength. We have developed an analytical approach for contact strength of hole selective contacts which represents the requirements on doping, thickness of the contact layer, and electrode work-function for a given illumination. First, the numerical model is cali-brated with the experimental data for a wide range of illumination (0.01 Sun - 1.0 Sun) and then simulations have been fitted with analytical model. For the selective contact layer, we observe that only the total charge, rather than thickness and doping individually, matters. The work-function of the top electrode also contributes strongly to contact strength and can in principle substitute doped layer. This insightful metric will guide the solar cell technologists to better understand the carrier selective contacts and to maximize the cell performance not only at standard test conditions (STC), but also at low light illuminations.

  • Details
  • Metrics
Type
research article
DOI
10.1016/j.solener.2022.08.047
Web of Science ID

WOS:000862848200005

Author(s)
Sharma, Rupendra Kumar
Boccard, Mathieu  
Holovsky, Jakub  
Date Issued

2022-09-15

Publisher

PERGAMON-ELSEVIER SCIENCE LTD

Published in
Solar Energy
Volume

244

Start page

168

End page

174

Subjects

Energy & Fuels

•

silicon solar cells

•

carrier selective contacts

•

contact strength

•

heterojunctions

•

device simulation

•

photovoltaic devices

•

performance

•

molybdenum

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

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PV-LAB  
Available on Infoscience
November 7, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/191913
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