This study presents a general methodology and an experimental approach to identify the gas components within laser-induced cavitation bubbles. A needle electrode inside the cavitation bubble, which introduces low electric energy into the bubble, produces a homogenous plasma discharge inside the vapor cavity. The primary bubble dynamics remain identical while the rebound bubble becomes about twice as large when a discharge is applied. The effect of non-condensable gases and the electric charge on bubble dynamics is explored theoretically, and the role of the electric charge is found to be significant. Optical emission spectroscopy reveals the evolution of emission lines from gases inside bubbles. H lines and OH lines are persistently observed in all cases, providing a dominant presence of water vapor. The results also confirm that the gases, which are initially present in the water rather than transported from the water, contribute to the optical emission characteristics with different dissolved gases.