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research article

Triggered incommensurate transition in PbHfO3

Burkovsky, Roman G.
•
Bronwald, Iurii
•
Andronikova, Dada
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July 29, 2019
Physical Review B

We report a type of structural phase transitions in dielectric materials: the triggered incommensurate (IC) transition. We demonstrate evidence for such a transition in the perovskite antiferroelectric PbHfO3 by means of single-crystal x-ray diffraction, diffuse, and inelastic-scattering experiments, which we interpret using the Landau theory of phase transitions. This transition is not driven by an IC soft mode, as is the case for the majority of IC dielectrics, but by the soft mode associated with a different, coexisting order parameter related to antiferrodistortive (AFD) tilts of the oxygen octahedra. When cooling from the high-temperature cubic phase these two order parameters are established simultaneously and discontinuously at T-IC approximate to 468 K. Two lattice instabilities are present in the cubic phase: AFD instability with critical temperature T-0 approximate to 441 K and ferroelectric instability with T-0 approximate to 408 K. The IC instability is absent. The analysis of the transition mechanism within the Landau theory of coupled order parameters indicates that the transition is of triggered character, conditioned upon the attractive biquadratic coupling between the IC modulation and the AFD octahedral tilts, and is driven by the AFD soft mode.

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Type
research article
DOI
10.1103/PhysRevB.100.014107
Web of Science ID

WOS:000477884800001

Author(s)
Burkovsky, Roman G.
Bronwald, Iurii
Andronikova, Dada
Lityagin, Georgiy
Piecha, Julita
Souliou, Sofia-Michaela
Majchrowski, Andrzej
Filimonov, Alexey
Rudskoy, Andrey
Roleder, Krystian
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Date Issued

2019-07-29

Publisher

AMER PHYSICAL SOC

Published in
Physical Review B
Volume

100

Issue

1

Article Number

014107

Subjects

Materials Science, Multidisciplinary

•

Physics, Applied

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Physics, Condensed Matter

•

Materials Science

•

Physics

•

structural phase-transformation

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temperature-dependence

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neutron-scattering

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diffuse-scattering

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srtio3

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pbzro3

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
CIME  
Available on Infoscience
August 13, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/159736
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