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  4. Negative plasmon dispersion in 2H-NbS2 beyond the charge-density-wave interpretation
 
research article

Negative plasmon dispersion in 2H-NbS2 beyond the charge-density-wave interpretation

Cudazzo, Pierluigi
•
Mueller, Eric
•
Habenicht, Carsten
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2016
New Journal Of Physics

We examine the experimental and theoretical electron-energy loss spectra in 2H-Cu0.2NbS2 and find that the 1 eV plasmon in this material does not exhibit the regular positive quadratic plasmon dispersion that would be expected for a normal broad-parabolic-band system. Instead we find a nearly non-dispersing plasmon in the momentum-transfer range q < 0.35 angstrom(-1). We argue that for a stoichiometric pure 2H-NbS2 the dispersion relation is expected to have a negative slope as is the case for other transition-metal dichalcogenides. The presence of Cu impurities, required to stabilize the crystal growth, tends to shift the negative plasmon dispersion into a positive one, but the doping level in the current system is small enough to result in a nearly-non-dispersing plasmon. We conclude that a negative-slope plasmon dispersion is not connected with the existence of a charge-density-wave order in transition metal dichalcogenides.

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Type
research article
DOI
10.1088/1367-2630/18/10/103050
Web of Science ID

WOS:000387155700001

Author(s)
Cudazzo, Pierluigi
Mueller, Eric
Habenicht, Carsten
Gatti, Matteo
Berger, Helmuth  
Knupfer, Martin
Rubio, Angel
Huotari, Simo
Date Issued

2016

Publisher

Iop Publishing Ltd

Published in
New Journal Of Physics
Volume

18

Article Number

103050

Subjects

plasmons

•

electro-energy-loss-spectroscopy

•

layered-materials

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSE  
Available on Infoscience
January 24, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/133735
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