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research article
Palladium-Catalyzed Enantioselective Narasaka-Heck Reaction/Direct C−H Alkylation of Arenes: Iminoarylation of Alkenes
A palladium-catalyzed reaction of g,d-unsaturated oxime esters with oxadiazoles afforded dihydropyrroles in good to excellent yields through an intramolecular iminopalladation/intermolecular direct heteroarene C-H alkylation cascade. This unprecedented iminoarylation of alkenes was subsequently realized in an enantioselective manner in the presence of a chiral bidentate phosphine ligand (Synphos).
Type
research article
Web of Science ID
WOS:000406385200062
Author(s)
Date Issued
2017
Publisher
Published in
Volume
56
Issue
32
Start page
9577
End page
9581
Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
Available on Infoscience
July 31, 2017
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